SUPERMAN Vs. BATMAN (Batman: The Brave and The Bold)

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Batman: The Brave and The Bold - Season 3 - Episode 5 - "Battle of the Superheroes!"

Main Plot: Following fights with Lex Luthor, Metallo, El Gar-Kur, Mister Mxyzptlk, and Toyman, Superman is infected with a Red Kryptonite necklace secretly given to Lois Lane by Lex Luthor which causes Superman to become evil. Now Batman must work with Krypto to hold off Superman until the effects of the Red Kryptonite wear off.

Source: Wikipedia